Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer–Moest Reaction under Flow Conditions,Chemistry - A European Journal

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Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer–Moest Reaction under Flow Conditions
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2019-11-19 , DOI: 10.1002/chem.201905028
Diego E. Collin ₁ , Ana A. Folgueiras‐Amador ₁ , Derek Pletcher ₁ , Mark E. Light ₁ , Bruno Linclau ₁ , Richard C. D. Brown ₁

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Cubane has been known about for more than half a century, but methods for direct functionalization of commercial cubane derivatives remain somewhat limited. The possibility of using electrochemical methods to transform cubane carboxylic acids presented an intriguing possibility, leading to the development of anodic decarboxylative ether formation in flow. The image, created by Noémie Collin, shows an ammonite fossil merged with an “Ammonite” flow electrolysis cell; electricity drives oxidation of the carboxylate functionality to form cubyl ethers. More information can be found in the Communication by B. Linclau, R. C. D. Brown, et al. (DOI: 10.1002/chem.201904479).

中文翻译：

Cubane电化学：在流动条件下使用Hofer-Moest反应将Cuban羧酸直接转化为烷氧基Cubanes

古巴人已经知道了半个多世纪，但是用于商业古巴衍生物的直接功能化的方法仍然受到一定的限制。使用电化学方法转化古巴羧酸的可能性提出了一种引人入胜的可能性，从而导致了流动中阳极脱羧醚形成的发展。由诺米·柯林（NoémieCollin）制作的图像显示了一种铵铁化石与“氨铁”流式电解池的融合。电驱动羧酸盐官能团的氧化以形成立方醚。可以在B.Linclau，R.C.D.Brown等人的来文中找到更多信息。（DOI：10.1002 / chem.201904479）。

更新日期：2019-11-19

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