Applied Catalysis B: Environment and Energy ( IF 20.2 ) Pub Date : 2019-11-12 , DOI: 10.1016/j.apcatb.2019.118426 Dandan Zhu , Qixing Zhou
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In this study, a series of NCN/BiWO (NCN = N-doped Graphitic Carbon Nitride, BiWO = Bi2WO6) were fabricated successfully, which were characterized by XRD, TEM, FTIR, BET, UV-vis spectrometry, XPS and PL. Under visible light irradiation, the optimum mass ratio of 60% NCN/BiWO can reach 93.1% removal efficiency of phenol within 5 h, which was about 6.9 times as that pure Bi2WO6. And the degradation rate constant of 60% NCN/BiWO (2.6726 min-1) was about 18.5 times as that of pure Bi2WO6(0.1442 min-1). According to the result of UV-vis absorption spectra, VB-XPS spectra and photoelectrochemistry performance, the photocatalytic mechanism of 60% NCN/BiWO were revealed, indicating that the narrow band gap of 60% NCN/BiWO is the main factor on high photocatalytic activity. The stable and recyclable properties also were done, showing highly suitable for practical application.
中文翻译:
![](https://static.x-mol.com/jcss/images/paperTranslation.png)
N掺杂石墨化氮化碳光催化剂修饰的新型Bi 2 WO 6在可见光下有效降解苯酚
在这项研究中,成功地制造了一系列的NCN / BiWO(NCN = N掺杂的石墨碳氮化物,BiWO = Bi 2 WO 6),并通过XRD,TEM,FTIR,BET,UV-vis光谱,XPS和XS进行了表征。 PL。在可见光照射下,最佳质量比为60%的NCN / BiWO可以在5小时内达到93.1%的苯酚去除率,约为纯Bi 2 WO 6的6.9倍。60%NCN / BiWO(2.6726 min -1)的降解速率常数约为纯Bi 2 WO 6(0.1442 min -1)的降解速率常数的18.5倍。)。根据紫外可见吸收光谱,VB-XPS光谱和光电化学性能的结果,揭示了60%NCN / BiWO的光催化机理,表明60%NCN / BiWO的窄带隙是影响高光催化性能的主要因素。活动。还实现了稳定和可回收的特性,显示出非常适合实际应用。