Sn13-Oxo Clusters with an Open Hollow Structural Motif and Decorated by Different Functional Ligands.,Inorganic Chemistry

当前位置： X-MOL 学术 › Inorg. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Sn13-Oxo Clusters with an Open Hollow Structural Motif and Decorated by Different Functional Ligands.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2019-11-11 , DOI: 10.1021/acs.inorgchem.9b02474
Yu Zhu ₁ , Jian Zhang ₁ , Lei Zhang ₁

Affiliation

The first open hollow Sn13-oxo cluster family has been successfully prepared and characterized. These Sn13 clusters contain a {Sn7} moiety that is similar to the basic structure unit of rutile SnO2. Interestingly, the Sn13 clusters show labile coordination sites on the edge, which could be functionalized by different ligands. With the different decorated types of functionalized ligands, the open hollow Sn13 clusters present different structural details and framework diameters. The presented results provide a new open hollow structural motif of tin-oxo clusters and also a good platform for their ligand functionalization.

中文翻译：

Sn13-Oxo团簇具有开放的空心结构基序，并由不同的功能性配体修饰。

第一个开放的空心Sn13-oxo簇家族已成功制备和表征。这些Sn13簇包含{Sn7}部分，与金红石SnO2的基本结构单元相似。有趣的是，Sn13团簇在边缘显示出不稳定的配位点，可以通过不同的配体将其官能化。具有不同修饰类型的官能化配体，开放的空心Sn13团簇具有不同的结构细节和骨架直径。提出的结果提供了锡-氧簇的新的开放的空心结构图案，也为它们的配体功能化提供了良好的平台。

更新日期：2019-11-13

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南