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Efficient Electrocatalytic CO2 Fixation by Nanoconfined Enzymes via a C3-to-C4 Reaction That Is Favored over H2 Production
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-11-11 , DOI: 10.1021/acscatal.9b03532
Giorgio Morello 1 , Bhavin Siritanaratkul 1 , Clare F. Megarity 1 , Fraser A. Armstrong 1
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-11-11 , DOI: 10.1021/acscatal.9b03532
Giorgio Morello 1 , Bhavin Siritanaratkul 1 , Clare F. Megarity 1 , Fraser A. Armstrong 1
Affiliation
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Reduction of CO2 and its direct entry into organic chemistry is achieved efficiently and in a highly visible way using a metal oxide electrode in which two enzyme catalysts, one for electrochemically regenerating reduced nicotinamide adenine dinucleotide phosphate and the other for assimilating CO2 and converting pyruvate (C3) to malate (C4), are entrapped within its nanopores. The resulting reversible electrocatalysis is exploited to construct a solar CO2 reduction/water-splitting device producing O2 and C4 with high faradaic efficiency.
中文翻译:
高效电CO 2经由C3至C4的反应通过固定化酶Nanoconfined即优于ħ 2生产
使用金属氧化物电极可有效且高度可见地实现CO 2的还原并直接进入有机化学,该电极中的两种酶催化剂,一种用于电化学还原还原的烟酰胺腺嘌呤二核苷酸磷酸,另一种用于化学吸收CO 2并转化丙酮酸。 (C3)至苹果酸(C4),被截留在其纳米孔内。利用所得的可逆电催化来构造太阳能法CO 2还原/水分解装置,以高法拉第效率产生O 2和C 4。
更新日期:2019-11-13
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
高效电CO 2经由C3至C4的反应通过固定化酶Nanoconfined即优于ħ 2生产
使用金属氧化物电极可有效且高度可见地实现CO 2的还原并直接进入有机化学,该电极中的两种酶催化剂,一种用于电化学还原还原的烟酰胺腺嘌呤二核苷酸磷酸,另一种用于化学吸收CO 2并转化丙酮酸。 (C3)至苹果酸(C4),被截留在其纳米孔内。利用所得的可逆电催化来构造太阳能法CO 2还原/水分解装置,以高法拉第效率产生O 2和C 4。