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An amino-functionalized metal–organic framework nanosheet array as a battery-type electrode for an advanced supercapattery
Dalton Transactions ( IF 3.5 ) Pub Date : 2019-11-04 , DOI: 10.1039/c9dt03821c Qin Li 1, 2, 3, 4, 5 , Jiaojiao Zhou 1, 2, 3, 4, 5 , Rui Liu 6, 7, 8, 9, 10 , Lei Han 1, 2, 3, 4, 5
Dalton Transactions ( IF 3.5 ) Pub Date : 2019-11-04 , DOI: 10.1039/c9dt03821c Qin Li 1, 2, 3, 4, 5 , Jiaojiao Zhou 1, 2, 3, 4, 5 , Rui Liu 6, 7, 8, 9, 10 , Lei Han 1, 2, 3, 4, 5
Affiliation
An amino-functionalized metal–organic framework nanosheet array supported on nickel foam (NH2-Co-MOF-NS/NF) was fabricated and served as a binder-free battery-type electrode, which exhibited maximum areal specific capacities of 6.7 C cm−2 (1861 μA h cm−2) and 2.9 C cm−2 (806 μA h cm−2) in a three-electrode device and in a supercapattery device, respectively. Moreover, the advanced supercapattery device delivered a high energy density of 0.351 mW h cm−2 at a power density of 1.70 mW cm−2, with superior capacity retention of 91.8% after 5000 cycles. This work can provide an efficient strategy to construct amino-functionalized 2D MOF nanosheets for energy storage and conversion.
中文翻译:
氨基官能化的金属-有机骨架纳米片阵列作为高级超级电池的电池型电极
制备了支持在泡沫镍(NH 2 -Co-MOF-NS / NF)上的氨基官能化金属-有机骨架纳米片阵列,并用作无粘合剂的电池型电极,其最大面积比容量为6.7 C cm -2(1861μA高厘米-2)和2.9ç厘米-2(806μA高厘米-2分别)在三电极装置和在supercapattery设备。此外,先进的超级电池装置以1.70 mW cm -2的功率密度提供了0.351 mW h cm -2的高能量密度。,在5000次循环后具有91.8%的卓越容量保持率。这项工作可以提供一种有效的策略来构建用于能量存储和转换的氨基官能化2D MOF纳米片。
更新日期:2019-11-04
中文翻译:
氨基官能化的金属-有机骨架纳米片阵列作为高级超级电池的电池型电极
制备了支持在泡沫镍(NH 2 -Co-MOF-NS / NF)上的氨基官能化金属-有机骨架纳米片阵列,并用作无粘合剂的电池型电极,其最大面积比容量为6.7 C cm -2(1861μA高厘米-2)和2.9ç厘米-2(806μA高厘米-2分别)在三电极装置和在supercapattery设备。此外,先进的超级电池装置以1.70 mW cm -2的功率密度提供了0.351 mW h cm -2的高能量密度。,在5000次循环后具有91.8%的卓越容量保持率。这项工作可以提供一种有效的策略来构建用于能量存储和转换的氨基官能化2D MOF纳米片。