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Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-10-21 , DOI: 10.1039/c9cc07943b
Rory Devlin 1, 2, 3, 4 , Jonathan Sperry 1, 2, 3, 4
Chemical Communications ( IF 4.3 ) Pub Date : 2019-10-21 , DOI: 10.1039/c9cc07943b
Rory Devlin 1, 2, 3, 4 , Jonathan Sperry 1, 2, 3, 4
Affiliation
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Indole and the anthocyanin orientalin proceed through a unique cascade sequence that leads to nudicaulins I and II in 92% yield. This biomimetic synthesis confirms the biosynthesis proposal for these structurally unprecedented flavoalkaloids that play a key role in the colour range displayed by the Iceland poppy.
中文翻译:
冰岛罂粟罂粟nudicaule †仿生合成Nudicaulins I和II,黄色颜料†
吲哚和花色苷东方香精通过独特的级联序列进行操作,从而以92%的收率得到了芥子油苷I和II。这种仿生合成证实了这些结构上前所未有的黄素生物碱的生物合成提议,这些黄素生物碱在冰岛罂粟所显示的颜色范围中起关键作用。
更新日期:2019-11-07
中文翻译:

冰岛罂粟罂粟nudicaule †仿生合成Nudicaulins I和II,黄色颜料†
吲哚和花色苷东方香精通过独特的级联序列进行操作,从而以92%的收率得到了芥子油苷I和II。这种仿生合成证实了这些结构上前所未有的黄素生物碱的生物合成提议,这些黄素生物碱在冰岛罂粟所显示的颜色范围中起关键作用。