Adducts of triangular silver(i) 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization†,Dalton Transactions

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Adducts of triangular silver(i) 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization†
Dalton Transactions ( IF 3.5 ) Pub Date : 2019-10-15 , DOI: 10.1039/c9dt03344k
Rongrong Liu _{1,

2,

3,

4} , Wenhua Zhang _{1,

2,

3,

4} , Donghui Wei _{1,

2,

3,

4} , Jing-Huo Chen _{1,

2,

3,

4} , Seik Weng Ng _{5,

6,

7,

8} , Guang Yang _{1,

2,

3,

4}

Affiliation

π-Acidic triangular silver(I) 3,5-bis(trifluoromethyl)pyrazolate (Ag₃pz₃) can form 1 : 1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak Ag⋯S and Ag⋯C contacts and sometimes by π–π stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.

中文翻译：

三角形的银的加合物（我）3,5-双（三氟甲基）吡唑特与噻吩衍生物：脱硫的弱相互作用模型†

π-酸性三角银（I）3,5-双（三氟甲基）吡唑酸酯（Ag ₃ pz ₃）可以与二苯并噻吩（DBT），4,6-二甲基二苯并噻吩（DMDBT），苯并噻吩（BT）和2,5-二甲基噻吩（DMT）通过弱的Ag⋯S和Ag⋯C接触（有时通过π–π堆积）来稳定，因此对于某些吸附脱硫过程而言可能代表弱的相互作用模型。

更新日期：2019-11-06

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