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New approach to the synthesis of tetrazole-containing buta-1,3-diynes: The total synthesis of 1,4-Bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2019-09-27 , DOI: 10.1016/j.tetlet.2019.151217
George K. Belousov , Alexander V. Zuraev

An approach for the total synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne was reported. Developed approach to the synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne can be used for obtaining different 2,5-bis(tetrazol-5-yl)-disubstituted five-membered heterocycles (e.g. thiophenes, pyrroles, furans etc.), as well as tetrazole-containing monomers for the synthesis of new types of electroconductive and high energetic polymers.



中文翻译:

合成含四唑的buta-1,3-diynes的新方法:1,4-双(2-(丁基)-2 H-四唑-5-基)buta-1,3-的全合成狄恩

报道了一种全合成1,4-双(2-(丁基)-2 H-四唑-5-基)丁-1,3-二炔的方法。合成的1,4-双(2-(丁基)-2 H-四唑-5-基)丁1,3-二炔的合成方法可用于获得不同的2,5-双(四唑- 5-基)二取代的五元杂环(例如噻吩,吡咯,呋喃等),以及用于合成新型导电和高能聚合物的含四唑的单体。

更新日期:2019-09-28
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