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Bismuth oxyiodide microflower-derived catalysts for efficient CO2 electroreduction in a wide negative potential region†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-09-23 , DOI: 10.1039/c9cc05089b
Peng Fei Liu 1, 2, 3, 4, 5 , Meng Yang Zu 1, 2, 3, 4, 5 , Li Rong Zheng 6, 7, 8, 9 , Hua Gui Yang 1, 2, 3, 4, 5
Affiliation  

It is of paramount importance to design and develop highly active and selective electrocatalysts for the CO2 reduction reaction. Herein, we obtained bismuth-based catalysts consisting of oxidized Bi2O2CO3 and metallic Bi featuring local shortened inter-layer Bi–Bi bonds from in situ reduction of bismuth oxyiodide (BiOI) microflowers, which showed over 90% formate faradaic efficiency in a wide negative potential region.

中文翻译:

氧化碘化铋微花衍生的催化剂,可在较宽的负电势区域有效地还原CO 2

设计和开发用于CO 2还原反应的高活性和选择性电催化剂至关重要。在这里,我们从原位还原氧化碘化铋(BiOI)微花获得了由氧化的Bi 2 O 2 CO 3和具有局部缩短的层间Bi-Bi键的金属Bi组成的铋基催化剂,其甲酸法拉第效率超过90%。在广泛的负电位区域。
更新日期:2019-10-10
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