tert-Butyl Nitrite (TBN), a Multitasking Reagent in Organic Synthesis.,Chemistry - An Asian Journal

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tert-Butyl Nitrite (TBN), a Multitasking Reagent in Organic Synthesis.
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2019-10-21 , DOI: 10.1002/asia.201901072
Anjali Dahiya ₁ , Ashish Kumar Sahoo ₁ , Tipu Alam ₁ , Bhisma K Patel ₁

Affiliation

The upsurge interest in the development of efficient methodologies for the construction of nitrogen-containing frameworks via the use of expedient reagents have been creating a renaissance in contemporary organic chemistry. In this perspective, tertbutyl nitrite (TBN) is an emerging building block. Due to its unique structural features, it shows differential reactivity under different reaction conditions. These diverse reactivities have resulted in the construction of a diverse array of complex N-containing molecules. The primary objective of the present review is to bring the latest findings of TBN in terms of its applications in reactions (oxidation, diazotization, nitrosation, nitration, oximation, N-synthon, and miscellaneous reactions) into the limelight. For simplicity and brevity, reactions in each section are explained with the mechanism of formation and selected examples are given.

中文翻译：

叔丁基亚硝酸盐（TBN），有机合成中的多任务试剂。

对通过使用方便的试剂来构建含氮骨架的有效方法开发的兴趣日益浓厚，这已在当代有机化学领域掀起了一场复兴。从这个角度来看，亚硝酸叔丁酯（TBN）是新兴的构建基块。由于其独特的结构特征，它在不同的反应条件下显示出不同的反应性。这些不同的反应性导致了复杂的含氮分子的多样化阵列的构建。本综述的主要目的是使TBN在反应（氧化，重氮化，亚硝化，硝化，肟化，N-合成子和其他反应）中的应用方面的最新发现成为人们关注的焦点。为了简洁起见，

更新日期：2019-10-21

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