Four-component radical-dual-difunctionalization (RDD) and decarbonylative alkylative peroxidation of two different alkenes with aliphatic aldehydes and TBHP†,Chemical Communications

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Four-component radical-dual-difunctionalization (RDD) and decarbonylative alkylative peroxidation of two different alkenes with aliphatic aldehydes and TBHP†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-09-03 , DOI: 10.1039/c9cc05764a
Ren-Xiang Liu _{1,

2,

3,

4} , Feng Zhang _{1,

2,

3,

4,

5} , Yong Peng _{1,

2,

3,

4} , Luo Yang _{1,

2,

3,

4}

Affiliation

From difunctionalization of a single alkene to radical-dual-difunctionalization of two different alkenes! Abundant aliphatic aldehydes were readily decarbonylated into alkyl radicals for the cascade construction of C(sp³)–C(sp³), C(sp³)–C(sp³) and C(sp³)–O bonds via double radical addition and radical–radical coupling, following the intrinsic nucleophilic/electrophilic reactivity of both the radicals and alkenes.

中文翻译：

两种不同烯烃与脂肪醛和TBHP的四组分自由基-双-双官能化（RDD）和脱羰基烷基化过氧化†

从单个烯烃的双官能化到两个不同烯烃的自由基-双-双官能化！丰富的脂族醛很容易通过双自由基加成反应而脱羰基化为C（sp ³）–C（sp ³），C（sp ³）–C（sp ³）和C（sp ³）–O键的级联结构的烷基。自由基和烯烃之间固有的亲核/亲电反应性，然后进行自由基-自由基偶联。

更新日期：2019-10-03

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