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镍(II)配合物的可逆热致变色和单晶到单晶的转变。
ACS Omega ( IF 3.7 ) Pub Date : 2019-08-15 , DOI: 10.1021/acsomega.9b01263 Jayaraman Pitchaimani 1 , Subramanian Karthikeyan 2 , Narayanan Lakshminarasimhan 3 , Savarimuthu Philip Anthony 4 , Dohyun Moon 5 , Vedichi Madhu 1
ACS Omega ( IF 3.7 ) Pub Date : 2019-08-15 , DOI: 10.1021/acsomega.9b01263 Jayaraman Pitchaimani 1 , Subramanian Karthikeyan 2 , Narayanan Lakshminarasimhan 3 , Savarimuthu Philip Anthony 4 , Dohyun Moon 5 , Vedichi Madhu 1
Affiliation
由于N-Ni(II)键长和配体的细微变化,分子Ni(II)-NNN钳形配合物(1)在加热和冷却时显示出前所未有的可逆单晶至单晶转变和颜色变化构象。紫外可见,热重,差示扫描量热法,单晶结构数据,与温度有关的粉末X射线衍射和拉曼光谱和计算研究支持了Ni(II)配合物随温度的结构变化。
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更新日期:2019-08-15
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