Iron-Catalyzed Decarboxylative Olefination of Unstrained Carbon-Carbon Bonds Relying on Alkoxyl Radical Induced Cascade.,Organic Letters

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Iron-Catalyzed Decarboxylative Olefination of Unstrained Carbon-Carbon Bonds Relying on Alkoxyl Radical Induced Cascade.
Organic Letters ( IF 4.9 ) Pub Date : 2019-08-26 00:00:00 , DOI: 10.1021/acs.orglett.9b02675
Pin Gao ₁ , Hao Wu ₁ , Jun-Cheng Yang ₁ , Li Na Guo ₁

Affiliation

An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.

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