当前位置: X-MOL 学术ACS Sustain. Chem. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Environmentally Friendly Protocol for the Oxidative Iodofunctionalization of Olefins in a Green Solvent
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2019-09-06 , DOI: 10.1021/acssuschemeng.9b04298
Wei Yi 1 , Peng-Fei Wang 1 , Meng Lu 1 , Qian-Qian Liu 1 , Xue Bai 1 , Kai-Die Chen 1 , Jing-Wen Zhang 1 , Gong-Qing Liu 1
Affiliation  

An environmentally friendly iodofunctionalization of olefins for the synthesis of various iodinated products was developed via the oxidative umpolung of iodide using I2O5 as the inorganic oxidant. The distinct advantages of this protocol over all previous methods include no generation of organic byproducts and the use of a green solvent, thus greatly reducing the environmental impact. Additionally, mild reaction conditions, good yields, and easy-to-operate features make the current reaction system a more attractive method for the synthesis of a variety of medicinal and agrochemical compounds of interest.

中文翻译:

绿色溶剂中烯烃氧化碘官能化的环保协议

通过使用I 2 O 5作为无机氧化剂的碘化物的氧化反应,开发了用于合成各种碘化产物的烯烃的环保碘官能化反应。与所有以前的方法相比,该协议的显着优势包括不会产生有机副产物和使用绿色溶剂,从而大大减少了对环境的影响。此外,温和的反应条件,良好的收率和易于操作的特性使当前的反应系统成为合成各种目标药物和农用化学化合物的更具吸引力的方法。
更新日期:2019-09-07
down
wechat
bug