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Formation of a thin and continuous MOF membrane with 2-D MOF nanosheets as seeds via layer-by-layer growth†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-08-01 00:00:00 , DOI: 10.1039/c9cc04851k
Yingnan Ma 1, 2, 3, 4 , Zhaopeng Dong 1, 2, 3, 4 , Meng You 1, 2, 3, 4 , Yufeng Zhang 1, 2, 3, 4 , Xianshe Feng 5, 6, 7, 8 , Xiaohua Ma 1, 2, 3, 4 , Jianqiang Meng 1, 2, 3, 4
Affiliation  

Current MOF composite membranes usually suffer from unduly thick MOF layers and poor adhesion with the polymer substrate. We prepared a thin MOF film (440 nm) on a polymer support with 2-D MOF nanosheets as seeds via a layer-by-layer growth. These 2-D MOF seeds not only provided bonding between the MOF film and the polymer substrate but also facilitated the formation of a continuous and defect-free MOF membrane, which demonstrated excellent performance in gas separation.

中文翻译:

通过逐层生长 以2-D MOF纳米片作为种子形成连续的薄MOF膜

当前的MOF复合膜通常具有过厚的MOF层和与聚合物基材的差的粘合性。我们通过一层一层的生长在具有2-D MOF纳米片作为种子的聚合物载体上制备了薄的MOF膜(440 nm)。这些2-D MOF种子不仅提供了MOF膜与聚合物基材之间的结合,而且还促进了连续且无缺陷的MOF膜的形成,在气体分离方面表现出出色的性能。
更新日期:2019-08-01
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