Ionic Liquids in Asymmetric Synthesis: An Overall View from Reaction Media to Supported Ionic Liquid Catalysis,ChemCatChem

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Ionic Liquids in Asymmetric Synthesis: An Overall View from Reaction Media to Supported Ionic Liquid Catalysis
ChemCatChem ( IF 3.8 ) Pub Date : 2018-06-08 , DOI: 10.1002/cctc.201701919
Babak Karimi _{1,

2} , Mina Tavakolian ₁ , Maryam Akbari ₁ , Fariborz Mansouri ₁

Affiliation

Ionic liquids, as a special class of organic compounds, have attracted ever‐growing interest in recent years. They have been employed in many organic transformations as a green alternative to volatile organic solvents and as a catalyst to modify catalytic activity and recyclability. Recent developments have demonstrated that ionic liquids might also have many benefits in asymmetric reactions. In this review, we survey the use of ionic liquids in asymmetric transformations, including the use of ionic liquids as reaction media in asymmetric reactions, ionic‐liquid‐tagged chiral catalysts for use in asymmetric synthesis, and supported ionic liquid catalysts in asymmetric transformations.

中文翻译：

不对称合成中的离子液体：从反应介质到支持的离子液体催化的总体观点

离子液体作为一类特殊的有机化合物，近年来引起了越来越多的关注。它们已在许多有机转化中用作挥发性有机溶剂的绿色替代品，并用作修饰催化活性和可回收性的催化剂。最近的发展表明，离子液体在不对称反应中也可能具有许多好处。在这篇综述中，我们调查了离子液体在不对称转化中的使用，包括离子液体在不对称反应中作为反应介质的使用，离子液体标记的用于不对称合成的手性催化剂以及负载型离子液体催化剂在不对称转化中的使用。

更新日期：2018-06-08

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