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Catalyst-Free One-Pot Synthesis of Unsymmetrical Five- and Six-Membered Sulfur-Annulated Heterocyclic Perylene Diimides for Electron-Transporting Property
Organic Letters ( IF 4.9 ) Pub Date : 2019-06-27 00:00:00 , DOI: 10.1021/acs.orglett.9b01847 Lingcheng Chen 1 , Pengjie Xia 1 , Tian Du 2 , Yunfeng Deng 2 , Yi Xiao 1
Organic Letters ( IF 4.9 ) Pub Date : 2019-06-27 00:00:00 , DOI: 10.1021/acs.orglett.9b01847 Lingcheng Chen 1 , Pengjie Xia 1 , Tian Du 2 , Yunfeng Deng 2 , Yi Xiao 1
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A novel unsymmetrical five- and six-membered sulfur-annulated heterocyclic perylene diimides (PDI) derivative was obtained by a one-pot and catalyst-free synthesis in a high yield. The unsymmetrical PDI exhibits a noteworthy bathochromic shift absorption of up to 700 nm and a low-lying lowest unoccupied molecular orbital level of −3.99 eV. The compound owns a complete planar structure and a high electron mobility of 4.8 × 10–3 cm2 V–1 s–1 in solution-processable top-gate/bottom-contact organic field-effect transistor device.
中文翻译：
无催化剂一锅法合成不对称的五元和六元硫环杂环Per二酰亚胺的电子输运性质
通过一锅法和无催化剂合成以高收率获得了新颖的不对称五元和六元硫环杂环ulated二酰亚胺（PDI）衍生物。非对称PDI表现出高达700 nm的值得注意的红移位移吸收和低至-3.99 eV的最低最低未占据分子轨道能级。该化合物在溶液可处理的顶栅/底接触有机场效应晶体管器件中拥有完整的平面结构和4.8×10 –3 cm 2 V –1 s –1的高电子迁移率。
更新日期：2019-06-27
中文翻译：
无催化剂一锅法合成不对称的五元和六元硫环杂环Per二酰亚胺的电子输运性质
通过一锅法和无催化剂合成以高收率获得了新颖的不对称五元和六元硫环杂环ulated二酰亚胺（PDI）衍生物。非对称PDI表现出高达700 nm的值得注意的红移位移吸收和低至-3.99 eV的最低最低未占据分子轨道能级。该化合物在溶液可处理的顶栅/底接触有机场效应晶体管器件中拥有完整的平面结构和4.8×10 –3 cm 2 V –1 s –1的高电子迁移率。
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