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Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2019-06-25 00:00:00 , DOI: 10.1021/acs.inorgchem.9b01340 Yuya Ashida , Kazuya Arashiba , Hiromasa Tanaka 1 , Akihito Egi 2 , Kazunari Nakajima , Kazunari Yoshizawa 2 , Yoshiaki Nishibayashi
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2019-06-25 00:00:00 , DOI: 10.1021/acs.inorgchem.9b01340 Yuya Ashida , Kazuya Arashiba , Hiromasa Tanaka 1 , Akihito Egi 2 , Kazunari Nakajima , Kazunari Yoshizawa 2 , Yoshiaki Nishibayashi
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We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.
中文翻译：
使用简单的单齿和双齿膦作为辅助配体的钼催化氨形成
我们已经发现使用简单且可商购的简单且可商购的单齿和双齿膦作为辅助配体的钼催化的氨形成。由[MoI 3（THF）3 ]原位生成的钼配合物和相应的膦（如PMePh 2和1,5-双（二苯基膦基）戊烷）有效地促进了氨的形成。
更新日期：2019-06-25
中文翻译：
使用简单的单齿和双齿膦作为辅助配体的钼催化氨形成
我们已经发现使用简单且可商购的简单且可商购的单齿和双齿膦作为辅助配体的钼催化的氨形成。由[MoI 3（THF）3 ]原位生成的钼配合物和相应的膦（如PMePh 2和1,5-双（二苯基膦基）戊烷）有效地促进了氨的形成。
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