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KxCs1−xPbBr3 NCs glasses possessing super optical properties and stability for white light emitting diodes
Chemical Engineering Journal ( IF 13.3 ) Pub Date : 2019-06-21 , DOI: 10.1016/j.cej.2019.122031
Guangzhan Shao , Shengnan Liu , Ling Ding , Zelong Zhang , Weidong Xiang , Xiaojuan Liang

CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) glasses formed utilizing conventional melt-quenching with a subsequent heat-treatment method demonstrate excellent performance and can resist temperature and light irradiation; further, CsPbX3 NCs glasses have improved stability in air and water when compared to traditional way. Nevertheless, one of the fatal disadvantages of CsPbX3 NCs glasses are their low photoluminescence quantum yields (PLQY). Here, we demonstrate a new avenue that K+ ions doped CsPbBr3 NCs glasses (K-CPB NCs glasses) systems utilizing KxCs1−xPbBr3 (x = 0, 0.2, 0.4, 0.6, 0.8, 1) NCs glasses, and we surprisingly find that K0.6Cs0.4PbBr3 NCs glass reaches the highest PLQY of 62% when the molar ratio of K+/Cs+ = 0.6/0.4. Meanwhile, in comparative experiments, we have noticed that K0.6Cs0.4PbBr3 NCs glass has better water resistance and thermal stability than CsPbBr3 NCs glasses what we had before. K-CPB NCs glasses has a significantly improved applications scope for cesium lead halide perovskite in the field of photoelectricity, such as solar cells and perovskite light-emitting diodes (PeLEDs). In addition, we have successfully fabricated the pure phase of KPbBr3 NCs glass and its existence has been proven via a series of representational means, consequently, this research opens the door for the further study of perovskite materials. Fortunately, K-CPB NCs glasses perform better in optical third-order nonlinearity, and we believe these findings will promote its applications in nonlinear optoelectronic devices. Ultimately, white LEDs (WLEDs) has been successfully equipped with K0.6Cs0.4PbBr3 NCs glass, which presents excellent optical parameters.



中文翻译:

具有超光学性能和白色发光二极管稳定性的K x Cs 1-x PbBr 3 NCs眼镜

利用常规的熔融淬火和随后的热处理方法形成的CsPbX 3(X = Cl,Br,I)纳米晶体(NCs)玻璃表现出优异的性能,并且可以抵抗温度和光辐射。此外,与传统方式相比,CsPbX 3 NCs眼镜在空气和水中的稳定性得到了改善。然而,CsPbX 3 NCs玻璃的致命缺点之一是其低的光致发光量子产率(PLQY)。在这里,我们演示了利用K x Cs 1-x PbBr 3掺杂K +离子的CsPbBr 3 NCs眼镜(K-CPB NCs眼镜)的新途径。(x = 0、0.2、0.4、0.6、0.8、1 )NCs玻璃,我们惊奇地发现,当K + / Cs +  = 0.6时,K 0.6 Cs 0.4 PbBr 3 NCs玻璃达到62%的最高PLQY /0.4。同时,在对比实验中,我们注意到K 0.6 Cs 0.4 PbBr 3 NCs玻璃具有比CsPbBr 3更好的耐水性和热稳定性。NCs眼镜我们以前拥有过。K-CPB NCs玻璃在太阳能电池和钙钛矿发光二极管(PeLEDs)等光电领域中具有显着改善的卤化铯铅钙钛矿的应用范围。此外,我们已经成功地制备了KPbBr 3 NCs玻璃的纯相,并通过一系列代表性方法证明了其存在,因此,该研究为钙钛矿材料的进一步研究打开了大门。幸运的是,K-CPB NCs眼镜在光学三阶非线性方面表现更好,我们相信这些发现将促进其在非线性光电器件中的应用。最终,白光LED(WLED)成功地配备了K 0.6 Cs 0.4 PbBr 3 NCs玻璃,具有出色的光学参数。

更新日期:2019-06-21
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