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Visible-Light-Promoted, Catalyst-Free Gomberg–Bachmann Reaction: Synthesis of Biaryls
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2019-06-20 00:00:00 , DOI: 10.1021/acs.joc.9b00557 Juyoung Lee , Boseok Hong , Anna Lee
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2019-06-20 00:00:00 , DOI: 10.1021/acs.joc.9b00557 Juyoung Lee , Boseok Hong , Anna Lee
Biaryls were synthesized via a novel visible-light-promoted Gomberg–Bachmann reaction that does not require a photosensitizer or any metal reagents. The formation of an electron donor–acceptor complex between aryl diazonium salts and pyridine allows, under visible-light irradiation, the synthesis of biaryls in moderate-to-high yields.
中文翻译:
可见光促进的,无催化剂的Gomberg-Bachmann反应:联芳烃的合成
联芳基是通过不需要光敏剂或任何金属试剂的新型可见光促进的Gomberg-Bachmann反应合成的。在芳基重氮盐和吡啶之间形成电子供体-受体配合物,可以在可见光照射下以中等至高收率合成联芳基。
更新日期:2019-06-20
中文翻译:
可见光促进的,无催化剂的Gomberg-Bachmann反应:联芳烃的合成
联芳基是通过不需要光敏剂或任何金属试剂的新型可见光促进的Gomberg-Bachmann反应合成的。在芳基重氮盐和吡啶之间形成电子供体-受体配合物,可以在可见光照射下以中等至高收率合成联芳基。