Rapid glycosylation of 2′-benzoylphenyl glycosides promoted by TfOH†,Organic Chemistry Frontiers

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Rapid glycosylation of 2′-benzoylphenyl glycosides promoted by TfOH†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2019-06-19 00:00:00 , DOI: 10.1039/c9qo00629j
Da-Ke Liu _{1,

2,

3,

4,

5} , De-Cai Xiong _{1,

2,

3,

4,

5} , Xia Wu _{1,

2,

3,

4,

5} , Qin Li _{1,

2,

3,

4,

5} , Xin-Shan Ye _{1,

2,

3,

4,

5}

Affiliation

A new glycosylation protocol based on 2′-benzoylphenyl glycosides has been developed. These glycosyl donors could be rapidly activated by TfOH at room temperature. The donors are readily available. The reaction exhibited a broad substrate scope and coupled products were obtained in high yields.

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