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Redox‐Active Monopyrrolotetrathiafulvalene‐Based Rotaxane Incorporating the Dihydroazulene/Vinylheptafulvene Photo/Thermoswitch
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2019-07-02 , DOI: 10.1002/ejoc.201900690 Martin Drøhse Kilde 1 , Rikke Kristensen 2 , Gunnar Olsen 2 , Jan O. Jeppesen 2 , Mogens Brøndsted Nielsen 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2019-07-02 , DOI: 10.1002/ejoc.201900690 Martin Drøhse Kilde 1 , Rikke Kristensen 2 , Gunnar Olsen 2 , Jan O. Jeppesen 2 , Mogens Brøndsted Nielsen 1
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A [2]rotaxane incorporating a monopyrrolo‐tetrathiafulvalene (green) unit that is encircled by a cyclobis(paraquat‐p‐phenylene) ring (blue) and containing a photoactive dihydroazulene (DHA) as the stopper group (yellow) was prepared. The DHA and its vinylheptafulvene (VHF) photoisomer both act as stopper groups, preventing dethreading of the ring. The kinetics of the thermal VHF‐to‐DHA conversion was influenced strongly by the positively charged ring.
中文翻译：
基于氧化还原活性的基于单吡咯并四硫富瓦烯的轮烷与二氢氮杂烯/乙烯基庚七烯照片/热敏开关
制备了一种[2]轮烷，其中并入了一个单吡咯并四硫富瓦烯（绿色）单元，该单元被环双（百草枯对苯）环（蓝色）环绕，并包含光敏性二氢氮杂烯（DHA）作为终止基团（黄色）。DHA及其乙烯基七氟戊烯（VHF）的光异构体均充当塞基，从而防止环脱线。VHF到DHA的热转化动力学受到带正电荷的环的强烈影响。
更新日期：2019-07-02
中文翻译：
基于氧化还原活性的基于单吡咯并四硫富瓦烯的轮烷与二氢氮杂烯/乙烯基庚七烯照片/热敏开关
制备了一种[2]轮烷，其中并入了一个单吡咯并四硫富瓦烯（绿色）单元，该单元被环双（百草枯对苯）环（蓝色）环绕，并包含光敏性二氢氮杂烯（DHA）作为终止基团（黄色）。DHA及其乙烯基七氟戊烯（VHF）的光异构体均充当塞基，从而防止环脱线。VHF到DHA的热转化动力学受到带正电荷的环的强烈影响。
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