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A high-sensitive ratiometric luminescent thermometer based on dual-emission of carbon dots/Rhodamine B nanocomposite
Journal of Colloid and Interface Science ( IF 9.4 ) Pub Date : 2019-05-27 , DOI: 10.1016/j.jcis.2019.05.088
Zhenpeng Zhu , Zishan Sun , Ziying Guo , Xinguo Zhang , Zhan-chao Wu

A core-shell nanocomposite based on carbon dots (CD)/Rhodamine B (RhB) is realized by a facile method. The composite particles show spherical shape with narrow size distribution, non-agglomeration and smooth surface. The as-obtained nanocomposite shows the characteristic dual-emission of thermal-stable CD blue emission and thermal-sensitive RhB red emission at a single excitation wavelength. The fluorescence intensity ratio (FIR) is found to have a good linear relationship (R2 > 0.993) with temperature, while the corresponding maximum absolute and relative sensitivity is 2.01% K−1 and 1.39% K−1 in range of 283–373 K. The research provides a simple approach to create novel dual-emitting nanocomposites for temperature sensing application in micron-scale and biological field.



中文翻译:

基于碳点/若丹明B纳米复合材料双重发射的高灵敏度比例发光温度计

通过简便的方法实现了基于碳点(CD)/若丹明B(RhB)的核-壳纳米复合材料。复合颗粒呈球形,粒度分布窄,不团聚,表面光滑。如此获得的纳米复合材料在单个激发波长下表现出热稳定的CD蓝色发射和热敏RhB红色发射的双重发射特征。发现荧光强度比(FIR) 与温度具有良好的线性关系(R 2 > 0.993),而相应的最大绝对和相对灵敏度分别为2.01%K -1和1.39%K -1 在283–373 K范围内。该研究提供了一种简单的方法来创建新颖的双发射纳米复合材料,用于微米级和生物领域的温度传感应用。

更新日期:2019-05-27
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