Hyper-Cross-Linked Polymer on the Hollow Conjugated Microporous Polymer Platform: A Heterogeneous Catalytic System for Poly(caprolactone) Synthesis,ACS Macro Letters

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Hyper-Cross-Linked Polymer on the Hollow Conjugated Microporous Polymer Platform: A Heterogeneous Catalytic System for Poly(caprolactone) Synthesis
ACS Macro Letters ( IF 5.1 ) Pub Date : 2019-05-24 00:00:00 , DOI: 10.1021/acsmacrolett.9b00229
Sung Jae Choi ₁ , Eun Ho Choi ₁ , Changsik Song ₁ , Yoon-Joo Ko ₂ , Sang Moon Lee ₃ , Hae Jin Kim ₃ , Hye-Young Jang ₄ , Seung Uk Son ₁

Affiliation

This work shows that the shape-controlled microporous organic polymer (MOP) can be utilized for the morphological engineering of another class of MOP materials. The morphology of a hyper-cross-linked polymer (HCP) was successfully engineered on the hollow conjugated microporous polymer (CMP). Through the postsynthetic modification of HCP bearing BINOLs (HCP-B) on the hollow CMP-like material (H-CMPL), the HCP bearing BINOL phosphoric acid (HCP-BP) was engineered on the H-CMPL platform. The resultant [email protected] showed good catalytic performance as a heterogeneous catalytic system and excellent recyclability in the ring-opening polymerization of ε-caprolactones to poly(caprolactone).

中文翻译：

中空共轭微孔聚合物平台上的超交联聚合物：用于聚（己内酯）合成的多相催化系统

这项工作表明，形状可控的微孔有机聚合物（MOP）可用于另一类MOP材料的形态工程。在中空共轭微孔聚合物 (CMP) 上成功设计了超交联聚合物 (HCP) 的形态。通过在空心类 CMP 材料 (H-CMPL) 上对带有 HCP 的 BINOL (HCP-B) 进行后合成修饰，在 H-CMPL 平台上设计了带有 HCP 的 BINOL 磷酸 (HCP-BP)。所得的 [email protected] 作为非均相催化体系表现出良好的催化性能，并且在 ε-己内酯开环聚合成聚（己内酯）的过程中表现出优异的可回收性。

更新日期：2019-05-24

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