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Copper-Catalyzed Regioselective Borylfluoromethylation of Alkenes
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-05-23 00:00:00 , DOI: 10.1021/acscatal.9b01530
Nuo-Yi Wu 1 , Xiu-Hua Xu 2 , Feng-Ling Qing 1, 2
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-05-23 00:00:00 , DOI: 10.1021/acscatal.9b01530
Nuo-Yi Wu 1 , Xiu-Hua Xu 2 , Feng-Ling Qing 1, 2
Affiliation
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A copper-catalyzed borylfluoromethylation of alkenes with fluoromethyl iodide and diboron reagents was disclosed. This protocol afforded the previously unknown and synthetically useful borylfluoromethylated alkanes in good yields and excellent regioselectivity. Its synthetic application was illustrated through the derivatization of organoboron products and preparation of monofluorinated ibuprofen.
中文翻译：
铜催化烯烃的区域选择性硼氟烷基甲基化
公开了用氟甲基碘和二硼试剂进行的铜的烯烃的硼烷基氟甲基化。该方案以良好的收率和优异的区域选择性提供了以前未知的和合成上有用的硼烷基氟甲基化的烷烃。通过有机硼产品的衍生化和单氟布洛芬的制备说明了其合成应用。
更新日期：2019-05-23
中文翻译：
铜催化烯烃的区域选择性硼氟烷基甲基化
公开了用氟甲基碘和二硼试剂进行的铜的烯烃的硼烷基氟甲基化。该方案以良好的收率和优异的区域选择性提供了以前未知的和合成上有用的硼烷基氟甲基化的烷烃。通过有机硼产品的衍生化和单氟布洛芬的制备说明了其合成应用。
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