Unexpected Vinylcyclopropane Rearrangement: New Strategies toward Skipped Dienes Using Sulfonium Ylides,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Unexpected Vinylcyclopropane Rearrangement: New Strategies toward Skipped Dienes Using Sulfonium Ylides
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2019-06-06 , DOI: 10.1002/ejoc.201900720
Maximilien Richald ₁ , Arnaud Delbrassinne ₁ , Raphaël Robiette ₁

Affiliation

An unexpected rearrangement of vinylcyclopropane into a skipped diene proceeds at room temperature with high selectivity. This transformation was used to develop two complementary strategies toward skipped dienes using sulfonium ylides.