An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction†,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-05-07 00:00:00 , DOI: 10.1039/c9cc02174d
Ming-Liang Gao _{1,

2,

3,

4} , Mei-Hong Qi _{1,

2,

3,

4} , Lin Liu _{1,

2,

3,

4} , Zheng-Bo Han _{1,

2,

3,

4}

Affiliation

A novel strategy has been developed to construct a highly stable core–shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π–π stacking interaction. This hybrid material with spatially isolated antagonistic acid–base sites can effectively catalyze the deacetalization–Knoevenagel condensation cascade reaction.

中文翻译：

异常稳定的核-壳MOF / COF双功能催化剂，可高效进行级联脱缩醛-Knoevenagel缩合反应†

已经开发了一种新颖的策略，可以通过强大的π-π堆积相互作用来构建高度稳定的核-壳MOF @ COF（PCN-222-Co @ TpPa-1）双功能催化剂。这种在空间上具有隔离的拮抗酸基位点的杂化材料可以有效催化脱缩醛-Knoevenagel缩合级联反应。

更新日期：2019-05-07

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南