Cover Feature: Perfluorophenyl‐Directed Giant Porphyrin J‐Aggregates (Chem. Eur. J. 30/2019),Chemistry - A European Journal

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Cover Feature: Perfluorophenyl‐Directed Giant Porphyrin J‐Aggregates (Chem. Eur. J. 30/2019)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2019-05-03 , DOI: 10.1002/chem.201901525
Mitsuhiko Morisue ₁ , Ikuya Ueno ₁ , Kunihiko Muraoka ₁ , Shun Omagari _{2,

3} , Takayuki Nakanishi _{2,

4} , Yasuchika Hasegawa ₂ , Takaaki Hikima ₅ , Sono Sasaki ₆

Affiliation

Perfluorophenyl‐terminated porphyrin self‐assembled into exceptionally large J‐aggregates in methylcyclohexane; a solvophobic effect of methylcyclohexane on perfluoroarene enhanced a self‐complementary quadrupolar interaction between the perfluorophenyl group and the porphyrin ring, and caused nucleation growth of needles. Eventually, the longitudinal size of porphyrin J‐aggregates reached up to several millimeters. More information can be found in the Full Paper by M. Morisue et al. on page 7322.

中文翻译：

封面特征：全氟苯基定向的巨型卟啉J聚集体（Chem.Eur.J.30 / 2019）

全氟苯基末端的卟啉在甲基环己烷中自组装成非常大的J聚集体；甲基环己烷对全氟芳烃的疏溶剂作用增强了全氟苯基和卟啉环之间的自互补四极相互作用，并导致针的成核生长。最终，卟啉J骨料的纵向尺寸达到几毫米。可以在M. Morisue等人的论文全文中找到更多信息。在7322页。

更新日期：2019-05-03

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