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Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2019-04-29 00:00:00 , DOI: 10.1039/c8cs00829a
Meili Ding 1, 2, 3, 4, 5 , Robinson W. Flaig 4, 6, 7, 8, 9 , Hai-Long Jiang 1, 2, 3, 4, 5 , Omar M. Yaghi 4, 6, 7, 8, 9
Affiliation  

Rapidly increasing atmospheric CO2 concentrations threaten human society, the natural environment, and the synergy between the two. In order to ameliorate the CO2 problem, carbon capture and conversion techniques have been proposed. Metal–organic framework (MOF)-based materials, a relatively new class of porous materials with unique structural features, high surface areas, chemical tunability and stability, have been extensively studied with respect to their applicability to such techniques. Recently, it has become apparent that the CO2 capture capabilities of MOF-based materials significantly boost their potential toward CO2 conversion. Furthermore, MOF-based materials’ well-defined structures greatly facilitate the understanding of structure–property relationships and their roles in CO2 capture and conversion. In this review, we provide a comprehensive account of significant progress in the design and synthesis of MOF-based materials, including MOFs, MOF composites and MOF derivatives, and their application to carbon capture and conversion. Special emphases on the relationships between CO2 capture capacities of MOF-based materials and their catalytic CO2 conversion performances are discussed.

中文翻译:

使用金属有机框架和基于MOF的材料进行碳捕获和转化

迅速增加的大气中CO 2浓度威胁着人类社会,自然环境以及两者之间的协同作用。为了改善CO 2问题,已经提出了碳捕获和转化技术。基于金属-有机骨架(MOF)的材料是一类相对较新的具有独特结构特征,高表面积,化学可调谐性和稳定性的多孔材料,已针对它们在此类技术中的适用性进行了广泛的研究。最近,很明显,基于MOF的材料的CO 2捕集能力显着提高了其向CO 2的潜力。转换。此外,基于MOF的材料定义明确的结构极大地促进了对结构-特性关系及其在CO 2捕获和转化中的作用的理解。在这篇综述中,我们全面介绍了基于MOF的材料(包括MOF,MOF复合材料和MOF衍生物)在设计和合成方面的重大进展,以及它们在碳捕获和转化中的应用。讨论了基于MOF的材料的CO 2捕集能力与其催化CO 2转化性能之间关系的特殊重点。
更新日期:2019-04-29
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