Electrochemistry Communications ( IF 4.7 ) Pub Date : 2019-04-27 , DOI: 10.1016/j.elecom.2019.04.011 Kewei Lu , Shan Lu , Tingting Gu , Xiangjun Zheng , Ke Ke , Xiaowei Li , Ruizhi Yang
Boron (B) and phosphorus (P) dual-doped carbon microspheres (BPC) were successfully synthesized from onium salts by a facile one-step pyrolysis method. When employed as the anode material for sodium (Na)-ion batteries (NIBs), the resulting BPC delivers a reversible capacity of 221.9 mAh g−1 at 50 mA g−1. Impressively, the BPC can still deliver a capacity of 102 mAh g−1 after 1500 cycles at 1 A g−1 with the capacity retention up to 78%. The high performance of the BPC can be attributed to the significantly increased defects and dilated interlayer distance induced by synergistically B and P co-doping.
中文翻译:
鎓盐衍生的B和P双掺杂碳微球作为高性能钠离子电池的负极材料
采用简便的一步法热解法成功地从鎓盐中合成了硼(B)和磷(P)双掺杂碳微球(BPC)。当作为阳极材料为钠(Na) -离子电池(钞)中使用,所得到的BPC提供的221.9毫安g的可逆容量- 1在50mA克- 1。令人印象深刻的BPC仍可递送的102毫安g的容量- 1 1 A G后1500个循环- 1与容量保持高达78%。BPC的高性能可归因于B和P协同掺杂共同引起的缺陷显着增加和层间距离增大。