Palladium/Norbornene Cooperative Catalysis.,Chemical Reviews

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Palladium/Norbornene Cooperative Catalysis.
Chemical Reviews ( IF 51.4 ) Pub Date : 2019-04-25 , DOI: 10.1021/acs.chemrev.9b00079
Jianchun Wang ₁ , Guangbin Dong ₁

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Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.

中文翻译：

钯/降冰片烯协同催化。

钯/降冰片烯协同催化已成为一种从容易获得的起始材料构建多官能化芳烃的独特方法。本综述对该领域进行了全面的概述，包括早期的化学计量研究、催化反应的发展以及在生物活性化合物和聚合物合成中的应用。催化反应部分根据反应引发方式分为两部分：Pd(0)引发反应和Pd(II)引发反应。

更新日期：2019-04-25

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