Prussian blue analogues (PBAs, A₂T[M(CN)₆], A = Li, K, Na; T = Fe, Co, Ni, Mn, Cu, etc.; M = Fe, Mn, Co, etc.) are a large family of materials with an open framework structure. In recent years, they have been intensively investigated as active materials in the field of energy conversion and storage, such as for alkaline‐ion batteries (lithium‐ion, LIBs; sodium‐ion, NIB; and potassium‐ion, KIBs), and as electrochemical catalysts. Nevertheless, few review papers have focused on the intrinsic chemical and structural properties of Prussian blue (PB) and its analogues. In this Review, a comprehensive insight into the PBAs in terms of their structural and chemical properties, and the effects of these properties on their materials synthesis and corresponding performance is provided.

中文翻译：

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普鲁士蓝类似物的化学性质，结构性质和储能应用

普鲁士蓝类似物（PBAs，A ₂ T [M（CN）₆ ]，A = Li，K，Na; T = Fe，Co，Ni，Mn，Cu等; M = Fe，Mn，Co等）是具有开放框架结构的大量材料。近年来，它们已在能量转换和存储领域作为活性材料进行了深入研究，例如用于碱性离子电池（锂离子，LIB，钠离子，NIB和钾离子，KIB），以及作为电化学催化剂。然而，很少有评论论文关注普鲁士蓝（PB）及其类似物的内在化学和结构性质。在本综述中，将对PBA的结构和化学性质以及这些性质对其材料合成和相应性能的影响提供全面的了解。