Herein, a series of Pd nanoparticles supported on Cu-MOFs (Cu₃(BTC)₂, FeCu-DMC) with pure Lewis acidity are synthesized for hydrogenative ring-rearrangement reaction of furanic aldehydes (furfural, 5-hydroxymethyl furfural) to cyclopentanone compounds (cyclopentanone, 3-hydroxymethyl cyclopentanone). For both furfural and 5-hydroxymethyl furfural, the hydrogenation rate catalyzed by the Pd/Cu-BTC is six times faster than Pd/FeCu-DMC, due to the higher dispersion of Pd nanoparticles. Meanwhile, Pd/Cu-BTC with strong acidity for the selectivity of cyclopentanone compounds is more than 90%, while as for Pd/FeCu-DMC, furanic alcohols (furfuryl alcohol, 2,5-bis(hydroxymethyl)furan) are only actually be obtained because weak acidity cannot incur subsequent hydrolysis reaction.

本文中，合成了一系列具有纯路易斯酸性的负载在Cu-MOFs（Cu ₃（BTC）₂，FeCu-DMC）上的Pd纳米颗粒，用于呋喃醛（糠醛，5-羟甲基糠醛）与环戊酮化合物的加氢环重排反应（环戊酮，3-羟甲基环戊酮）。对于糠醛和5-羟甲基糠醛，由于Pd纳米颗粒的分散性较高，因此Pd / Cu-BTC催化的氢化速率比Pd / FeCu-DMC快六倍。同时，具有强酸性的Pd / Cu-BTC对环戊酮化合物的选择性大于90％，而对于Pd / FeCu-DMC，呋喃醇（糠醇，2,5-双（羟甲基）呋喃）实际上只是由于弱酸性不能引起随后的水解反应，因此可以得到。