Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer,Journal of the American Chemical Society

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Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2019-04-08 , DOI: 10.1021/jacs.9b00171
Takashi Nakamura ₁ , Shinnosuke Tsukuda ₁ , Tatsuya Nabeshima ₁

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Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective inclusion of fullerenes ( Ka(C70)/ Ka(C60) > 100), utilizing their rigid scaffolds.

中文翻译：

由双臂双功能单体生成的双环连接 Saloph 带大环化合物

具有saloph单元作为壁的带状大环是通过带有邻苯二胺和水杨醛官能团的双臂双官能单体的双环连接产生的。Saloph 带大环化合物显示出独特的特性，例如利用其刚性支架选择性地包含富勒烯 (Ka(C70)/Ka(C60) > 100)。

更新日期：2019-04-08

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