Convergent Synthesis of Fluorene Derivatives by a Rhodium‐Catalyzed Stitching Reaction/Alkene Isomerization Sequence,Chemistry - A European Journal

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Convergent Synthesis of Fluorene Derivatives by a Rhodium‐Catalyzed Stitching Reaction/Alkene Isomerization Sequence
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2019-05-07 , DOI: 10.1002/chem.201901519
Masaki Nishida ₁ , Ryo Shintani ₁

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A convergent synthetic method for the synthesis of fluorene derivatives has been developed by devising a rhodium‐catalyzed stitching reaction/alkene isomerization sequence. The reactions proceed smoothly under mild conditions for a variety of substrate combinations, and extended π‐conjugation systems are also readily accessible by utilizing this synthetic method. Optical properties of the obtained fluorene derivatives have also been examined.

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