The Role of Ligands in the Chemical Synthesis and Applications of Inorganic Nanoparticles.,Chemical Reviews

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The Role of Ligands in the Chemical Synthesis and Applications of Inorganic Nanoparticles.
Chemical Reviews ( IF 51.4 ) Pub Date : 2019-03-28 , DOI: 10.1021/acs.chemrev.8b00733
Amelie Heuer-Jungemann ₁ , Neus Feliu _{2,

3} , Ioanna Bakaimi ₄ , Majd Hamaly ₅ , Alaaldin Alkilany _{3,

6} , Indranath Chakraborty ₃ , Atif Masood ₇ , Maria F Casula _{8,

9} , Athanasia Kostopoulou ₁₀ , Eunkeu Oh _{11,

12} , Kimihiro Susumu _{11,

12} , Michael H Stewart ₁₂ , Igor L Medintz ₁₃ , Emmanuel Stratakis ₁₀ , Wolfgang J Parak ₃ , Antonios G Kanaras ₁

Affiliation

School of Physics and Astronomy, Faculty of Engineering and Physical Sciences , University of Southampton , Southampton SO17 1BJ , U.K.
Department of Laboratory Medicine (LABMED) , Karolinska Institutet , Stockholm 171 77 , Sweden.
Fachbereich Physik, CHyN , Universität Hamburg , 22607 Hamburg , Germany.
School of Chemistry, Faculty of Engineering and Physical Sciences , University of Southampton , Southampton SO171BJ , U.K.
King Hussein Cancer Center , P. O. Box 1269, Al-Jubeiha, Amman 11941 , Jordan.
Department of Pharmaceutics & Pharmaceutical Technology, School of Pharmacy , The University of Jordan , Amman 11942 , Jordan.
Fachbereich Physik , Philipps Universität Marburg , 30357 Marburg , Germany.
INSTM and Department of Chemical and Geological Sciences , University of Cagliari , 09042 Monserrato , Cagliari , Italy.
Department of Mechanical, Chemical and Materials Engineering , University of Cagliari , Via Marengo 2 , 09123 Cagliari , Italy.
Institute of Electronic Structure and Laser , Foundation for Research and Technology-Hellas , Heraklion , 71110 Crete , Greece.
KeyW Corporation , Hanover , Maryland 21076 , United States.
Optical Sciences Division, Code 5600 , U.S. Naval Research Laboratory , Washington , D.C. 20375 , United States.
Center for Bio/Molecular Science and Engineering, Code 6900 , U.S. Naval Research Laboratory , Washington , D.C. 20375 , United States.

The design of nanoparticles is critical for their efficient use in many applications ranging from biomedicine to sensing and energy. While shape and size are responsible for the properties of the inorganic nanoparticle core, the choice of ligands is of utmost importance for the colloidal stability and function of the nanoparticles. Moreover, the selection of ligands employed in nanoparticle synthesis can determine their final size and shape. Ligands added after nanoparticle synthesis infer both new properties as well as provide enhanced colloidal stability. In this article, we provide a comprehensive review on the role of the ligands with respect to the nanoparticle morphology, stability, and function. We analyze the interaction of nanoparticle surface and ligands with different chemical groups, the types of bonding, the final dispersibility of ligand-coated nanoparticles in complex media, their reactivity, and their performance in biomedicine, photodetectors, photovoltaic devices, light-emitting devices, sensors, memory devices, thermoelectric applications, and catalysis.

中文翻译：

配体在无机纳米粒子化学合成和应用中的作用。

纳米颗粒的设计对于它们在从生物医学到传感和能量的许多应用中的有效使用至关重要。尽管形状和尺寸决定了无机纳米颗粒核的特性，但配体的选择对于纳米颗粒的胶体稳定性和功能至关重要。而且，在纳米颗粒合成中使用的配体的选择可以确定它们的最终尺寸和形状。纳米粒子合成后添加的配体既可以推断出新特性，又可以提供增强的胶体稳定性。在本文中，我们提供了有关配体在纳米颗粒形态，稳定性和功能方面的作用的全面综述。我们分析了具有不同化学基团，键合类型，

更新日期：2019-03-28

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