当前位置：
X-MOL 学术
›
Organometallics
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Reversible Binding of Ethylene and Propylene by Germylenes
Organometallics ( IF 2.5 ) Pub Date : 2019-03-28 , DOI: 10.1021/acs.organomet.9b00109 Kelly L. Gullett 1 , Ting Yi Lai 1 , Chia-Yuan Chen 1 , James C. Fettinger 1 , Philip P. Power 1
Organometallics ( IF 2.5 ) Pub Date : 2019-03-28 , DOI: 10.1021/acs.organomet.9b00109 Kelly L. Gullett 1 , Ting Yi Lai 1 , Chia-Yuan Chen 1 , James C. Fettinger 1 , Philip P. Power 1
Affiliation
|
The diarylgermylenes Ge(ArMe6)2 and Ge(AriPr4)2 (ArMe6 = C6H3-2,6-(C6H3-2,4,6-Me3)2), AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) are shown to react reversibly with ethylene. It is demonstrated that the more sterically crowded Ge(AriPr4)2 also reversibly binds propylene. The germirane products Ar2
GeCH2
CHR (Ar, R = ArMe6, H (1a), AriPr4, H (1b), and AriPr4, Me (1c)) were characterized via 1H and 13C NMR spectroscopy and by X-ray crystallography in the case of 1b. Thermolysis of Ge(AriPr4)2 under ethylene resulted in Ge–C bond homolysis and the formation of the digermene [(AriPr4)Ge(Et)]2 (1d). The thermodynamic parameters of the reactions were determined by variable-temperature 1H NMR spectroscopy.
中文翻译：
亚甲基对乙烯和丙烯的可逆结合
二芳基亚锗烷基Ge（Ar Me6）2和Ge（Ar i Pr4）2（Ar Me6 = C 6 H 3 -2,6-（C 6 H 3 -2,4,6-Me 3）2），Ar i Pr4＝ C 6 H 3 -2，6-（C 6 H 3 -2，6- i Pr 2）2）与乙烯可逆反应。结果表明，Ge（Ar i Pr4）2在空间上更拥挤。也可逆地结合丙烯。通过1 H和13 C NMR光谱表征了蓝宝石产物Ar 2 GeCH 2 CHR（Ar，R = Ar Me6，H（1a），Ar i Pr4，H（1b）和Ar i Pr4，Me（1c））。在1b的情况下通过X射线晶体学。乙烯下Ge（Ar i Pr4）2的热解导致Ge–C键均质化和Digermene [（Ar i Pr4）Ge（Et）] 2（1d）。反应的热力学参数通过可变温度1 H NMR光谱法确定。
更新日期：2019-03-28
GeCH2CHR (Ar, R = ArMe6, H (1a), AriPr4, H (1b), and AriPr4, Me (1c)) were characterized via 1H and 13C NMR spectroscopy and by X-ray crystallography in the case of 1b. Thermolysis of Ge(AriPr4)2 under ethylene resulted in Ge–C bond homolysis and the formation of the digermene [(AriPr4)Ge(Et)]2 (1d). The thermodynamic parameters of the reactions were determined by variable-temperature 1H NMR spectroscopy.
中文翻译：
亚甲基对乙烯和丙烯的可逆结合
二芳基亚锗烷基Ge（Ar Me6）2和Ge（Ar i Pr4）2（Ar Me6 = C 6 H 3 -2,6-（C 6 H 3 -2,4,6-Me 3）2），Ar i Pr4＝ C 6 H 3 -2，6-（C 6 H 3 -2，6- i Pr 2）2）与乙烯可逆反应。结果表明，Ge（Ar i Pr4）2在空间上更拥挤。也可逆地结合丙烯。通过1 H和13 C NMR光谱表征了蓝宝石产物Ar 2
GeCH 2 CHR（Ar，R = Ar Me6，H（1a），Ar i Pr4，H（1b）和Ar i Pr4，Me（1c））。在1b的情况下通过X射线晶体学。乙烯下Ge（Ar i Pr4）2的热解导致Ge–C键均质化和Digermene [（Ar i Pr4）Ge（Et）] 2（1d）。反应的热力学参数通过可变温度1 H NMR光谱法确定。
京公网安备 11010802027423号