Synthesis and Transformations of Nitrones for Organic Synthesis.,Chemical Reviews

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Synthesis and Transformations of Nitrones for Organic Synthesis.
Chemical Reviews ( IF 51.4 ) Pub Date : 2019-03-15 , DOI: 10.1021/acs.chemrev.8b00476
Shun-Ichi Murahashi ₁ , Yasushi Imada ₂

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Nitrones are important compounds and are highly useful in many aspects. The first part describes the methods for synthesis of nitrones, which are useful and environmentally friendly. Catalytic oxidations, condensations, and other useful reactions are described. The nitrones thus obtained are key intermediates for the synthesis of biologically important nitrogen compounds. The second part describes the fundamental transformations of nitrones, which will provide the strategies and means for the construction of nitrogen compounds. The reactions with nucleophiles or radicals, C-H functionalization, and various addition reactions are described. The last reactions are particularly important for highly selective carbon-carbon bond formations. 1,3-Dipolar cycloaddition reactions are excluded because the size of the review is limited and excellent reviews have been published in Chemical Reviews.

中文翻译：

用于有机合成的硝基的合成和转化。

硝基是重要的化合物，在许多方面都非常有用。第一部分描述了合成硝酮的方法，该方法有用且对环境友好。描述了催化氧化，缩合和其他有用的反应。如此获得的硝酮是合成生物学上重要的氮化合物的关键中间体。第二部分描述了硝酮的基本转化，这将为构建氮化合物提供策略和手段。描述了与亲核试剂或自由基的反应，CH官能化以及各种加成反应。最后的反应对于高度选择性的碳-碳键形成特别重要。1，

更新日期：2019-03-15

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