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Co doping induced photocurrent enhancement in photocatalyst MoS2
Catalysis Communications ( IF 3.4 ) Pub Date : 2019-03-14 , DOI: 10.1016/j.catcom.2019.03.014
Zhigang Pan , Zhonghuai Xia , Yaqiu Tao , Xiaodong Shen

A set of Co doped MoS2 photocatalysts were prepared by hydrothermal method and are used in photocatalytic degradation of methylene blue. A high consistency of the photocurrents and photocatalytic MB degradation are found. The photocurrents in MoS2 is improved greatly by Co doping, resulting in a high MB degradation up to 74% by 16% Co in molar ratio doped MoS2. A higher or lower Co doping increase the out-of plane interaction in MoS2, which reduces the active sites and the photocatlytic activity of these catalysts. The Co promotion in MoS2 are efficient in both decreasing the interlayer Van der Waals force and increasing the electron generation and transfer, thus the photoefficiency of MoS2.



中文翻译:

Co掺杂诱导光催化剂MoS 2中的光电流增强

通过水热法制备了一组Co掺杂的MoS 2光催化剂,并将其用于亚甲基蓝的光催化降解。发现光电流和光催化MB降解的高度一致性。通过Co掺杂大大提高了MoS 2中的光电流,导致摩尔比掺杂MoS 2达到16%Co时,MB降解率高达74%。较高或较低的Co掺杂会增加MoS 2中的平面外相互作用,从而降低这些催化剂的活性中心和光催化活性。共同促进的MoS 2是有效的在两个减小层间的范德华力及增加电子产生和转移,从而硫化钼的光电效率2

更新日期:2019-03-14
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