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Ytterbium Silicide Nanostructures Prepared by Pulsed Laser Ablation in Oven: Structural and Electrical Characterization
Materials Letters ( IF 2.7 ) Pub Date : 2019-07-01 , DOI: 10.1016/j.matlet.2019.03.032
Vladislav Dřínek , Zdeněk Remeš , Mariana Klementová , Lukáš Palatinus , Markéta Jarošová , Alois Lugstein , Masiar Sistani , Martin Koštejn , Věra Jandová , Radek Fajgar

Abstract Ytterbium silicide nanoobjects were synthetized using pulsed laser ablation in an oven at temperatures of 800 and 1000 °C. Ablation of divided target Si/Yb in a flow of Ar resulted in deposits which contained mostly ytterbium silicide nanowires, nanorods and nanoparticles. Single nanoparticles (800 °C) are identical with Yb3Si5 alloy; nanorods possess both a monoclinic phase not corresponding to any known structure in the phase diagram Yb-Si and a face-centered cubic structure close to the pure Yb but with a high Si content. At the temperature of 1000 °C, the studied nanorods and nanowires decorated by nanocrystals are practically amorphous, whereas the structure of those nanocrystals is close to that of the nanorods with the face-centered cubic structure prepared at 800 °C. Nanowire (1000 °C) is a semiconductor with ρ = 132.9 Ω.cm at room temperature, which is comparable to a heavily doped silicon.

中文翻译:

在烤箱中通过脉冲激光烧蚀制备的硅化镱纳米结构:结构和电学表征

摘要 在 800 和 1000 °C 的烘箱中使用脉冲激光烧蚀合成了硅化镱纳米物体。在 Ar 流中烧蚀分离的目标 Si/Yb 导致沉积物,其中主要包含硅化镱纳米线、纳米棒和纳米颗粒。单个纳米粒子(800°C)与 Yb3Si5 合金相同;纳米棒具有与 Yb-Si 相图中任何已知结构不对应的单斜相和接近纯 Yb 但具有高 Si 含量的面心立方结构。在 1000 °C 的温度下,所研究的纳米棒和由纳米晶体装饰的纳米线实际上是无定形的,而这些纳米晶体的结构与在 800 °C 下制备的面心立方结构的纳米棒的结构接近。纳米线 (1000 °C) 是一种 ρ = 132.9 Ω 的半导体。
更新日期:2019-07-01
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