Progress in the synthesis of perylene bisimide dyes,Organic Chemistry Frontiers

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Progress in the synthesis of perylene bisimide dyes
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2019-03-07 00:00:00 , DOI: 10.1039/c8qo01368c
Agnieszka Nowak-Król _{1,

2,

3,

4} , Frank Würthner _{1,

2,

3,

4}

Affiliation

With their versatile absorption, fluorescence, n-type semiconducting and (photo-)stability properties, perylene bisimides have evolved as the most investigated compounds among polycyclic aromatic hydrocarbons during the last decade. In this review we collect the results from about 200 original publications, reporting a plethora of new perylene bisimide derivatives whose properties widely enrich the possibility for the application of these dyes beyond traditional fields. While some applications are highlighted, different from other recent reviews, our focus here is on the advances in the synthetic methodologies that have afforded new bay functionalizations, recently addressed functionalizations at the ortho-positions to the carbonyl groups, and annulation of carbo- and heterocyclic units. An impressive number of perylene bisimide oligomers are highlighted as well which are connected by single bonds or spiro linkage or in a fused manner, leading to arrays with fascinating optical and electronic properties.

中文翻译：

ylene双酰亚胺染料的合成进展

versatile双酰亚胺具有通用的吸收，荧光，n型半导体和（光）稳定性，在过去的十年中已发展成为多环芳烃中研究最多的化合物。在本综述中，我们收集了约200篇原始出版物的结果，报告了过多的新型per双酰亚胺衍生物，这些衍生物的性能广泛地丰富了这些染料在传统领域以外的应用可能性。虽然突出显示了一些应用程序，但与最近的其他评论不同，但我们在这里的重点是合成方法的进展，这些方法提供了新的托架功能化，最近在邻位解决了功能化问题羰基的-位，以及碳环和杂环单元的环合。还突出显示了数量惊人的per双酰亚胺低聚物，它们通过单键或螺键连接或以熔融方式连接，从而形成具有引人入胜的光学和电子特性的阵列。

更新日期：2019-03-07

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