当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex.
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 1998-Apr-20 , DOI: 10.1002/(sici)1521-3773(19980420)37:7<945::aid-anie945>3.0.co;2-x
Daniel J. Mindiola , Christopher C. Cummins

Instead of azides, which can be explosive and poorly soluble in nonpolar solvents, azabicycloheptadienes can be used to synthesize nitrides. The reaction of diiodide 1 with the lithium amide 3 provides the red nitride 2 in 60 % yield with loss of lithium iodide and anthracene. The remaining iodo ligand in 2 can undergo an exchange reaction with lithium amide 3, but no more anthracene is released.

中文翻译:

通过蒽消除去质子化的2,3:5,6-二苯并-7-氮杂双环[2.2.1]庚-2,5-二烯作为氮的氮源:碘化物(氮化物)铬(VI)配合物的合成。

可以使用氮杂双环庚二烯代替叠氮化物(叠氮化物可能易爆且难溶于非极性溶剂),以合成氮化物。二碘化物1与酰胺化锂3的反应以60%的收率提供了红色氮化物2,同时损失了碘化锂和蒽。2中剩余的碘配体可与氨基锂3发生交换反应,但不再释放蒽。
更新日期:
down
wechat
bug