A rare example of a molecular species prepared by solvothermal synthesis is the macrocyclic cobalt phosphonate/carboxylate 1, whose structure is shown schematically. At low temperatures this compound displays spontaneous magnetization due to canted antiferromagnetic ordering, which is very unusual for a discrete molecular material.

中文翻译：

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倾斜反铁磁体{K2 [CoO3 PCH2 N（CH2 CO2）2]} 6⋅xH2 O的溶剂热合成。

通过溶剂热合成制备的分子种类的稀有实例是大环膦酸钴/羧酸钴1，其结构被示意性地示出。在低温下，由于倾斜的反铁磁有序，该化合物显示出自发磁化，这对于离散的分子材料而言非常罕见。