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Hydrogenation and Hydrolysis of Furfural to Furfuryl Alcohol, Cyclopentanone, and Cyclopentanol with a Heterogeneous Copper Catalyst in Water
Industrial & Engineering Chemistry Research ( IF 3.8 ) Pub Date : 2019-03-01 , DOI: 10.1021/acs.iecr.8b06217 Xuyang Zhou 1 , Zhipeng Feng 1 , Wanwan Guo 1 , Junmei Liu 1 , Ruyue Li 1 , Rizhi Chen 1 , Jun Huang 1
Industrial & Engineering Chemistry Research ( IF 3.8 ) Pub Date : 2019-03-01 , DOI: 10.1021/acs.iecr.8b06217 Xuyang Zhou 1 , Zhipeng Feng 1 , Wanwan Guo 1 , Junmei Liu 1 , Ruyue Li 1 , Rizhi Chen 1 , Jun Huang 1
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The selectivity of hydrogenation of furfural can be tuned to furfuryl alcohol, cyclopentanone, and cyclopentanol by tuning the reaction conditions with a Cu catalyst. Catalyzed by Cu0.4Mg5.6Al2, furfural can be hydrogenated and dehydrated smoothly to furfuryl alcohol, cyclopentanone, and cyclopentanol in high yields, respectively. At 110 °C and under 2.0 MPa H2 pressure, furfuryl alcohol can be obtained in 99.5% yield. Moreover, the Cu0.4Mg5.6Al2 catalyzed hydrogenation of furfural in water gave cyclopentanol in 98.6% yield. Additionally, cyclopentanone can also be obtained in 98.1% yield. The catalyst Cu0.4Mg5.6Al2 can be reused several times with only slightly deactivation. Additionally, the hydrogenation of furfural gave well to excellent yield of cyclopentanol in high concentration (15–30 wt % solution of furfural in water), which improved the practicability and efficiency of the process. The hydrogenation of furfural is high efficient, practical and green process of biomass application.
中文翻译：
非均相铜催化剂在水中将糠醛加氢水解为糠醇，环戊酮和环戊醇
糠醛氢化的选择性可以通过用Cu催化剂调节反应条件而调节为糠醇，环戊酮和环戊醇。在Cu 0.4 Mg 5.6 Al 2的催化下，糠醛可以被氢化，并分别以高收率平稳地脱水为糠醇，环戊酮和环戊醇。在110°C和2.0 MPa H 2压力下，糠醇的收率为99.5％。而且，Cu 0.4 Mg 5.6 Al 2催化糠醛在水中的氢化反应以98.6％的收率得到环戊醇。另外，还可以98.1％的产率获得环戊酮。催化剂Cu 0.4 Mg 5.6Al 2可以仅在稍微失活的情况下重复使用几次。另外，糠醛的氢化在高浓度（糠醛在水中的15-30 wt％的溶液）中具有出色的环戊醇收率，从而提高了该方法的实用性和效率。糠醛的氢化是生物质应用的高效，实用和绿色的过程。
更新日期：2019-03-02
中文翻译：
非均相铜催化剂在水中将糠醛加氢水解为糠醇，环戊酮和环戊醇
糠醛氢化的选择性可以通过用Cu催化剂调节反应条件而调节为糠醇，环戊酮和环戊醇。在Cu 0.4 Mg 5.6 Al 2的催化下，糠醛可以被氢化，并分别以高收率平稳地脱水为糠醇，环戊酮和环戊醇。在110°C和2.0 MPa H 2压力下，糠醇的收率为99.5％。而且，Cu 0.4 Mg 5.6 Al 2催化糠醛在水中的氢化反应以98.6％的收率得到环戊醇。另外，还可以98.1％的产率获得环戊酮。催化剂Cu 0.4 Mg 5.6Al 2可以仅在稍微失活的情况下重复使用几次。另外，糠醛的氢化在高浓度（糠醛在水中的15-30 wt％的溶液）中具有出色的环戊醇收率，从而提高了该方法的实用性和效率。糠醛的氢化是生物质应用的高效，实用和绿色的过程。
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