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Designing Lithium-Sulfur Cells with Practically Necessary Parameters
Joule ( IF 38.6 ) Pub Date : 2018-01-27 , DOI: 10.1016/j.joule.2018.01.002
Sheng-Heng Chung , Arumugam Manthiram

In the pursuit of high-energy-density batteries, there is tremendous appetite for developing the lithium-sulfur technology with high sulfur loading and content while keeping the electrolyte/sulfur (E/S) ratio low to be competitive with or surpass the current lithium-ion technology. However, very limited studies have focused on keeping these parameters at practically desirable ranges. Here, we present a lithium-sulfur cell with a coaxial-graphene-coated cotton-carbon (CGCC) cathode that displays excellent performance with high sulfur loading (57.6 mg cm−2), high sulfur content (75 wt %), and low E/S ratio (4.2 μL mg−1) simultaneously. The cell exhibits high areal capacity (31 mA hr cm−2) and areal energy density (66 mW hr cm−2) that exceed the areal capacity (4 mA hr cm−2) and areal energy density (10 mW hr cm−2) of a commercial LiCoO2 cathode with a high capacity-retention rate of 68% over 200 cycles.



中文翻译:

设计具有实际必要参数的锂硫电池

在追求高能量密度电池方面,发展具有高硫负载量和高含量同时保持较低的电解质/硫(E / S)比值以与现有锂竞争或超越的锂硫技术具有极大的胃口。离子技术。然而,非常有限的研究集中在将这些参数保持在实际期望的范围内。在这里,我们提出了一种锂硫电池,带有同轴石墨烯涂层的棉碳(CGCC)阴极,在高硫负荷(57.6 mg cm -2),高硫含量(75 wt%)和低硫含量下表现出优异的性能E / S比(4.2μLmg -1)同时。该电池展现出高的面容量(31 mA hr cm -2)和面能量密度(66 mW hr cm -2)超过了商用LiCoO 2阴极的面容量(4 mA hr cm -2)和面能量密度(10 mW hr cm -2),在200个循环中具有68%的高容量保持率。

更新日期:2018-01-27
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