Dalian Institute of Chemical PhysicsChinese Academy of Sciences Dalian 116023 China
University of Chinese Academy of Sciences Beijing 100049 China
Fujian Provincial Key Laboratory of Theoretical and Computational ChemistryCollege of Chemistry and Chemical EngineeringXiamen University Xiamen 361005 China
Pacific Northwest National Laboratory Richland WA 99352 USA
State Key Laboratory of CatalysisDalian Institute of Chemical PhysicsChinese Academy of Sciences Dalian 116023 China
Collaborative Innovation Centre of Chemistry for Energy Materials (iChEM⋅2011)Xiamen University Fujian 361005 China
Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair
Hydrogen uptake and release in arene–cycloalkane pairs is an attractive strategy for hydrogen storage but is hampered by the large enthalpy change associated with dehydrogenation. In their Communication (DOI: 10.1002/anie.201810945), P. Chen, T. He, A. Wu, and co‐workers describe how reversible hydrogen storage under moderate conditions is possible with a sodiated phenoxide–cyclohexanolate pair.
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