Prussian Blue Cathode Materials for Sodium‐Ion Batteries and Other Ion Batteries,Advanced Energy Materials

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Prussian Blue Cathode Materials for Sodium‐Ion Batteries and Other Ion Batteries
Advanced Energy Materials ( IF 24.4 ) Pub Date : 2018-01-29 , DOI: 10.1002/aenm.201702619
Jiangfeng Qian ₁ , Chen Wu ₁ , Yuliang Cao ₁ , Zifeng Ma ₂ , Yunhui Huang _{3,

4} , Xinping Ai ₁ , Hanxi Yang ₁

Affiliation

Sodium‐ion batteries (SIBs) are considered to be a low‐cost complement or competitor to Li‐ion batteries for large‐scale electric energy storage applications; however, their development has been less successful due to the lack of suitable host materials to enable reversible Na⁺ insertion reactions. Prussian blue analogs (PBAs) appear to be attractive candidates for SIB cathodes because of their open channel structure, compositional and electrochemical tunability. In this paper, the authors present a comprehensive review on the recent advances in the development of PBA frameworks as SIB cathodes with particular attention to the structure‐performance correlation of the PBA materials, and discuss the possible strategies to address the problems present in the SIB applications of PBAs. Also, the development of the PBA frameworks for the insertion cathodes of other monovalent and multivalent ions is briefly introduced, with the aim of providing a new insight into the design and development of new host materials for the next‐generation advanced batteries.

中文翻译：

钠离子电池和其他离子电池的普鲁士蓝阴极材料

钠离子电池（SIB）被认为是锂离子电池的低成本补充或竞争者，适用于大规模电能存储应用；然而，由于缺乏合适的基质材料来实现可逆的Na ⁺的开发，它们的开发不太成功。插入反应。普鲁士蓝类似物（PBA）似乎是SIB阴极的诱人候选物，因为它们具有开放通道结构，组成和电化学可调性。在本文中，作者对作为SIB阴极的PBA框架开发的最新进展进行了全面综述，并特别关注了PBA材料的结构性能相关性，并讨论了解决SIB中存在的问题的可能策略。 PBA的应用。此外，还简要介绍了用于其他单价和多价离子插入阴极的PBA框架的开发，目的是为下一代高级电池的新型主体材料的设计和开发提供新的见解。

更新日期：2018-01-29

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