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Front Cover: Photocatalytic Cycloadditions Enabled by a Lithium Perchlorate/Nitromethane Electrolyte Solution (Eur. J. Org. Chem. 6/2019)
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2019-02-05 , DOI: 10.1002/ejoc.201900164
Shingo Nagahara 1 , Hiroki Wakamatsu 1 , Yohei Okada 2 , Kazuhiro Chiba 1
Affiliation  

The Front Cover shows a schematic impression of our photocatalytic cycloadditions involving carbon–carbon bond formations. Our methodology has employed lithium perchlorate/nitromethane electrolyte solution and this unique “platform stage” has enabled the photocatalytic cycloadditions in the absence of an external sensitizer. When starting materials are spotlighted on the platform stage by intensive 250 W UV lamp, several cycloadditions, including [2 + 2], [3 + 2], and [4 + 2] formats, take place effectively to give the corresponding cycloadducts in high yields, respectively. More information can be found in the Communication by K. Chiba et al.
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中文翻译:

封面:高氯酸锂/硝基甲烷电解质溶液引起的光催化环加成反应(Eur。J. Org。Chem。6/2019)

封面显示了我们涉及碳-碳键形成的光催化环加成的示意图。我们的方法采用了高氯酸锂/硝基甲烷电解质溶液,这种独特的“平台阶段”使得能够在没有外部敏化剂的情况下进行光催化环加成反应。当用250 W强力紫外线灯在平台平台上聚焦起始原料时,有效地发生了几种环加成反应,包括[2 + 2],[3 + 2]和[4 + 2]形式,以得到高浓度的相应环加合物。产量分别。可以在K. Chiba等人的来文中找到更多信息。
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更新日期:2019-02-05
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