Catalysis Communications ( IF 3.4 ) Pub Date : 2019-02-05 , DOI: 10.1016/j.catcom.2019.01.003 Xiaofei Liang , Guanlong Wang , Tianyu Huo , Xiaoli Dong , Guowen Wang , Hongchao Ma , Hui Liang , Xiufang Zhang
The graphene (Gr)/PI (pyromellitic dianhydride (PMDA) modified g-C3N4) heterojunction was fabricated by a handy sonochemical method. After adding PMDA in the forming process of g-C3N4, the conduction position of obtained catalyst was lowered to −0.59 eV (closer to the Fermi level of Gr), which is beneficial for constructing high-efficient heterojunction with less energy loss. The photocatalytic efficiency of Gr/PI for Rodamine B (RhB) degradation was greatly enhanced compared with Gr/g-C3N4. The k of RhB removal on Gr/PI was 1.60 times as that of Gr/g-C3N4. The excellent photocatalytic ability of Gr/PI was mainly attributed to the effective separation of photogenerated electron-holes.
中文翻译:
gC 3 N 4的能带结构修饰,可有效构建异质结并增强可见光下的光催化能力
石墨烯(Gr)/ PI(均苯四甲酸二酐(PMDA)改性的gC 3 N 4)异质结是通过便捷的声化学方法制备的。在gC 3 N 4的形成过程中添加PMDA后,所得催化剂的导电位置降低至-0.59 eV(更接近于Gr的费米能级),这有利于构建具有更少能量损失的高效异质结。与Gr / gC 3 N 4相比,Gr / PI对罗丹明B(RhB)降解的光催化效率大大提高。在Gr / PI上去除RhB的k是Gr / gC 3 N 4的1.60倍。Gr / PI的优异的光催化能力主要归因于光生电子空穴的有效分离。