Food Chemistry ( IF 8.5 ) Pub Date : 2016-10-31 , DOI: 10.1016/j.foodchem.2016.10.138 Nathan Levien Vanier , Shanise Lisie Mello El Halal , Alvaro Renato Guerra Dias , Elessandra da Rosa Zavareze
During oxidation, the hydroxyl groups of starch molecules are first oxidized to carbonyl groups, then to carboxyl groups. The contents of the carbonyl and carboxyl groups in a starch molecule therefore indicate the extent of starch oxidation. The mechanisms of starch oxidation with different oxidizing agents, including sodium hypochlorite, hydrogen peroxide, ozone and sodium periodate, are described in this review. The effects of these oxidizing agents on the molecular, physicochemical, thermal, pasting and morphological properties of starch are described as well. In addition, the main industrial applications of oxidized starches are presented. The present review is important for understanding the effects of oxidation on starch properties, and this information may facilitate the development of novel oxidized starches for both food and non-food applications.
中文翻译:
氧化淀粉的分子结构,功能性及应用:综述
在氧化过程中,淀粉分子的羟基首先被氧化为羰基,然后被氧化为羧基。因此,淀粉分子中羰基和羧基的含量表明淀粉氧化的程度。本文综述了用不同氧化剂(包括次氯酸钠,过氧化氢,臭氧和高碘酸钠)氧化淀粉的机理。还描述了这些氧化剂对淀粉的分子,物理化学,热,糊化和形态学特性的影响。此外,还介绍了氧化淀粉的主要工业应用。本综述对于理解氧化对淀粉特性的影响非常重要,